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Crafting mono- and novel bis-methylated pyrroloquinoxaline derivatives from a shared precursor and its application in the total synthesis of marinoquinoline A

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Damai, Margarita, Guzzardi, Norman, Lewis, Viliyana, Rao, Zenobia X., Sykes, Daniel and Patel, Bhaven (2023) Crafting mono- and novel bis-methylated pyrroloquinoxaline derivatives from a shared precursor and its application in the total synthesis of marinoquinoline A. RSC Advances, 13 (42). pp. 29561-29567. ISSN 2046-2069

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Abstract

The synthesis of mono- and novel bis-methylated pyrrolo[1,2-a]quinoxalines through the addition of unstable methyl radicals to aryl isocyanides is described contingent upon the reaction conditions employed. The strategy has been effectively employed in the total synthesis of the natural product marinoquinoline A.

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8814:44943

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8814:44943

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Title:

Crafting mono- and novel bis-methylated pyrroloquinoxaline derivatives from a shared precursor and its application in the total synthesis of marinoquinoline A

Creators:

Damai, Margarita, Guzzardi, Norman, Lewis, Viliyana, Rao, Zenobia X., Sykes, Daniel and Patel, Bhaven

Identification Number:

10.1039/D3RA05952A

Official URL:

https://pubs.rsc.org/en/content/articlelanding/202...

Date:

10 October 2023

Subjects:

500 Natural Sciences and Mathematics > 540 Chemistry & allied sciences

Department:

School of Human Sciences