Photoinitiated coupling of dienes and monoolefins with pentacarbonyliron

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Photoinitiated coupling of dienes and monoolefins with pentacarbonyliron

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Salama, Ibrahim Hamed Ibrahim (1984) Photoinitiated coupling of dienes and monoolefins with pentacarbonyliron. Doctoral thesis, Polytechnic of North London.

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Abstract

The photoreaction of pentacarbonyliron with 1,3-diene/monoolefin mixtures results in C-C coupling of the two organic substrates, forming a six-carbon chain which is coordinated to the Fe (CO) 3 moiety in a 1-a,4-6-n3 fashion. Using various 1,3- dienes and monoolefins carrying methyl and carboalkoxy substituents, the wide applicability of this process is demonstrated.

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