o-Nitrosophenol complexes and their synthetic potential

Kensett, Malcolm James (1980) o-Nitrosophenol complexes and their synthetic potential. Doctoral thesis, Polytechnic of North London.

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Abstract / Description

Interaction of triphenylphosphine with Ni(XqO)2 (XqOH = 2-nitrosophenol, X = 4-chloro, 4-bromo, 4-methyl and 5-methoxy) resulted in deoxygenation to give mainly bis(2-triphenylphosphiniminophenolato) nickel(ll), Similarly the interaction of triphenyl phosphine with Zn(qO)2 (qOH = 5-methoxy-2- nitrosophenol) involved deoxygenation and formation of bis(2-triphenylphosphiniminophenolato)zinc(ll). Action of dilute hydrochloric acid on these complexes afforded the hydrochlorides of the corresponding N(2-hydroxybenzene)iminotriphenyl phosphoranes. The hydrochlorides on neutralisation with sodium carbonate gave, in most cases, the parent N(2-hydroxybenzene)- iminotriphenyl phosphorene.

Item Type: Thesis (Doctoral)
Additional Information: uk.bl.ethos.259221
Subjects: 500 Natural Sciences and Mathematics > 540 Chemistry & allied sciences
Department: School of Human Sciences
Depositing User: Maria White
Date Deposited: 06 Sep 2018 11:35
Last Modified: 06 Sep 2018 11:35
URI: http://repository.londonmet.ac.uk/id/eprint/2998

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