Lanthanide and transition metal complexes of nitrogen and oxygen donor macrocyclic ligands

Evagorou, Evagoras George (1994) Lanthanide and transition metal complexes of nitrogen and oxygen donor macrocyclic ligands. Doctoral thesis, University of North London.

Abstract

This thesis is concerned with the synthesis and characterisation of altogether twenty 18- and 24-membered macrocyclic ligands, incorporating the pyridyl and phenolic substituents in the cavity, coupled with their lanthanide and transition metal complexes. Initially a survey of the synthesis and characteristics of related macrocycles is presented. The application of lanthanide metal complexes as contrast agents for magnetic resonance imaging (MRI) is discussed.

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